Abstract: Tetramethylammonium Hydroxide Poison- ing during a Pallet Cleaning Demonstration: Seung-

نویسنده

  • Hyun PARK
چکیده

Tetramethylammonium (TMA) is a well-known ganglion blocker and was first extracted from the sea anemone in 1923. Today, TMA’s hydroxide, tetramethylammonium hydroxide (TMAH), is used as a developer, etchant and polishing agent in the semiconductor manufacturing process, as well as a surfactant to prevent agglomeration. One national survey found that about 20,000 tons of TMAH are being used in Korea each year. TMAH is a strong base, like sodium hydroxide. According to its Material Safety Data Sheet (MSDS), if TMAH solution contacts the skin, it can be fatal or cause serious burning or eye damage. Cases of poisoning and death by skin exposure to TMAH have previously been reported in Taiwan 10, . Recently, there was an accident in Korea in which the hands, arms and legs of a worker were exposed to a newly developed TMAH-containing cleaner, and the worker died within a few hours. This study examines the details and the reason for this accidental death due to acute poisoning resulting from exposure to TMAH based on the autopsy report.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

The use of tetramethylammonium hydroxide in the Zimmermann reaction.

The use of tetramethylammonium hydroxide (T.M.A.H.) in place of potassium hydroxide in the Zimmermann reaction has been investigated. Although various pure steroids have different colour equivalents, a comparison of the results of 17-ketosteroid and 17-hydroxycorticosteroid estimations on a series of urines showed that the differences for the two reagents were only small and may be ignored. Tet...

متن کامل

Elimination of error caused by hemolysis and bilirubin-induced color quenching in clinical radioimmunoassays.

In radioimmunoassays and radioassays for various constituents of serum, color quenching is a source of error when liquid-scintillation methods are used in samples that contain hemolyzed blood and samples from jaundiced patients. A quench correction can be made by using the External Standard Channels Ratio method and normalizing the ratios, or, alternatively, by chemical decolorization with tetr...

متن کامل

Polarographic determination of malononitrile.

A procedure is proposed for the determination of malononitrile by differential pulse polarography in methanolic 0.1M tetraethylammonium iodide/0.001M tetramethylammonium hydroxide as the supporting electrolyte. In this medium malononitrile is chemically converted into an electroactive species. With close control of timing of the steps in the procedure the error of the method is +/-1.5% in the c...

متن کامل

Green synthesis of shape-defined anatase TiO2 nanocrystals wholly exposed with {001} and {100} facets.

Anatase TiO(2) nanocuboids wholly exposed with high-energy {001} and {100} facets were successfully synthesized by a novel, environmentally benign synthetic strategy using acid-delaminated vermiculite (DVMT) and tetramethylammonium hydroxide as synergistic morphology-controlling reagents, where the DVMT layers act as effective hard template selectively stabilizing the {001} facets of TiO(2).

متن کامل

ThermalIy assisted hydrolysis and alkylation of lignins

Three different milled lignins isolated from bamboo, pine and beech, corresponding to the three different structural groups, have been subjected to pyrolysis in the presence of tetramethylammonium hydroxide (TMAH) and tetrabutylammonium hydroxide (TBAH). Pyrolysis of the lignins in the presence of TMAH releases the methyl esters and methyl ethers of the different lignin monomers. Several moieti...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2013